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Energy levels and Rotational Constants of the 4pσ B"^1Σ_u^+, 5pπ D"^1Π_u^- and 7pπ ^1Π_u^- states in H_2
http://hdl.handle.net/10087/1992
http://hdl.handle.net/10087/19922023b240-d042-4339-bdbf-28aade2b72e7
| 名前 / ファイル | ライセンス | アクション |
|---|---|---|
KJ00004436243.pdf (454.3 kB)
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| Item type | 紀要論文 / Departmental Bulletin Paper(1) | |||||
|---|---|---|---|---|---|---|
| 公開日 | 2007-12-20 | |||||
| タイトル | ||||||
| タイトル | Energy levels and Rotational Constants of the 4pσ B"^1Σ_u^+, 5pπ D"^1Π_u^- and 7pπ ^1Π_u^- states in H_2 | |||||
| 言語 | ||||||
| 言語 | eng | |||||
| キーワード | ||||||
| 主題Scheme | Other | |||||
| 主題 | B" | |||||
| キーワード | ||||||
| 主題Scheme | Other | |||||
| 主題 | D" | |||||
| キーワード | ||||||
| 主題Scheme | Other | |||||
| 主題 | 7pπ | |||||
| キーワード | ||||||
| 主題Scheme | Other | |||||
| 主題 | H_2 | |||||
| 著者 |
Takezawa, Sanzo
× Takezawa, Sanzo |
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| 抄録 | ||||||
| 内容記述タイプ | Abstract | |||||
| 内容記述 | The absorption bands of H_2, B"-X(4,0), D"-X(2,0) and 7pπ -X(1,0), observed around about 803 A, are investigated by using the high resolution spectrum with the reciprocal dispersion 0.6cm-1. This wavelength region is corresponding to the first ionization energy of H_2. Its spectrum are fairly complicate, because of overlapping or masking with many Rydberg bands, of which belong to high members of npσ -X and npπ -X. In this work, the previous line assignments of these bands are examined in detail and are partly modified under the assumption of the perturbation between 7pπ -X(v=1) and 5pπ D"(v=1) bands. The previously observed photoionization peak near the R(0) line of B"-X(4,0) band, 124 354.8cm^<-1> has been 2.7cm^<-1> less to be assigned as the Q(1) line of 7pπ -X(1,0); the J=1 level, 124 473.3cm^<-1>, is below the autoionizing level, 124 476.0cm^<-1> (H_a^+, v=0, J=1). In absorption the R(0) line of B"-X is just superimposed by the Q(1) line of 7pπ -X(1,0) band. This problem is interpreted by consideration of the rotational perturbation. For persuasive interpretation of this localized perturbation, the reliable energy levels and electronic potential curves are essential. The R-K-R potentials require the precise molecular constants for the construction. The rotational and vibrational constants of the three states are evaluated and discussed in this work. | |||||
| 書誌情報 |
群馬大学医療技術短期大学部紀要 巻 12, p. 117-126, 発行日 1992-03-31 |
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| ISSN | ||||||
| 収録物識別子タイプ | ISSN | |||||
| 収録物識別子 | 0389-7540 | |||||
| 書誌レコードID | ||||||
| 収録物識別子タイプ | NCID | |||||
| 収録物識別子 | AN00068340 | |||||
| フォーマット | ||||||
| 内容記述タイプ | Other | |||||
| 内容記述 | application/pdf | |||||
| 著者版フラグ | ||||||
| 出版タイプ | VoR | |||||
| 出版タイプResource | http://purl.org/coar/version/c_970fb48d4fbd8a85 | |||||
| 資源タイプ | ||||||
| 資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
| 資源タイプ | departmental bulletin paper | |||||
| 出版者 | ||||||
| 出版者 | 群馬大学医療技術短期大学部 | |||||
| 資源タイプ | ||||||
| 内容記述タイプ | Other | |||||
| 内容記述 | Departmental Bulletin Paper | |||||
| 更新日 | ||||||
| 日付 | 2017-03-27 | |||||
| 日付タイプ | Created | |||||
